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Efficient near-infrared (NIR) photopolymerization is promising for applications such as hydrogel bioprinting, composite manufacturing, and other technologies that benefit from deep light penetration and low-energy activation. Yet, design principles for...more » « lessFree, publicly-accessible full text available January 1, 2026
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A series of Ru( ii )-terpyridine complexes containing electron-donating bidentate ligands are able to effectively photodissociate nitrile ligands using red light. A spectroscopic investigation of these complexes reveal that they follow anti-energy gap law behavior, providing further evidence that population of 3 LF excited states is not necessary for photoinduced nitrile dissociation.more » « less
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